From the Cell to the Module
In order to make the appropriate voltages and outputs available for different applications, single solar cells are interconnected to form larger units. Cells connected in series have a higher voltage, while those connected in parallel produce more electric current. The interconnected solar cells are usually embedded in transparent Ethyl-Vinyl-Acetate, fitted with an aluminum or stainless steel frame and covered with transparent glass on the front side.
The typical power ratings of such solar modules are between 10 Wpeak and 100 Wpeak. The characteristic data refer to the standard test conditions of 1000 W/m² solar radiation at a cell temperature of 25° Celsius. The manufacturer's standard warranty of ten or more years is quite long and shows the high quality standards and life expectancy of today's products.
Natural Limits of Efficiency
In addition to optimizing the production processes, work is also being done to increase the level of efficiency, in order to lower the costs of solar cells. However, different loss mechanisms are setting limits on these plans. Basically, the different semiconductor materials or combinations are suited only for specific spectral ranges. Therefore a specific portion of the radiant energy cannot be used, because the light quanta (photons) do not have enough energy to "activate" the charge carriers. On the other hand, a certain amount of surplus photon energy is transformed into heat rather than into electrical energy. In addition to that, there are optical losses, such as the shadowing of the cell surface through contact with the glass surface or reflection of incoming rays on the cell surface. Other loss mechanisms are electrical resistance losses in the semiconductor and the connecting cable. The disrupting influence of material contamination, surface effects and crystal defects, however, are also significant.
Single loss mechanisms (photons with too little energy are not absorbed, surplus photon energy is transformed into heat) cannot be further improved because of inherent physical limits imposed by the materials themselves. This leads to a theoretical maximum level of efficiency, i.e. approximately 28% for crystal silicon.
New Directions
Surface structuring to reduce reflection loss: for example, construction of the cell surface in a pyramid structure, so that incoming light hits the surface several times. New material: for example, gallium arsenide (GaAs), cadmium telluride (CdTe) or copper indium selenide (CuInSe²).
Tandem or stacked cells: in order to be able to use a wide spectrum of radiation, different semiconductor materials, which are suited for different spectral ranges, will be arranged one on top of the other.
Concentrator cells: A higher light intensity will be focussed on the solar cells by the use of mirror and lens systems. This system tracks the sun, always using direct radiation.
MIS Inversion Layer cells: the inner electrical field are not produced by a p-n junction, but by the junction of a thin oxide layer to a semiconductor.
Grätzel cells: Electrochemical liquid cells with titanium dioxide as electrolytes and dye to improve light absorption.
Source: German Foundation for Solar Energy
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